Awọn ọja akọkọ wa: silikoni Amino, silikoni bulọki, silikoni hydrophilic, gbogbo emulsion silikoni wọn, imudara imudara iyara wetting, ifun omi (Fluorine ọfẹ, Erogba 6, Carbon 8), awọn kemikali fifọ demin (ABS, Enzyme, Olugbeja Spandex, yiyọ Manganese)

 

Emulsifiers le pin si awọn ẹka meji ti o da lori awọn orisun wọn: awọn nkan adayeba ati awọn ọja sintetiki. Gẹgẹbi awọn ohun-ini ti eto emulsion ti a ṣe ni awọn ipele meji, o le pin si awọn oriṣi meji: omi ninu epo (O / W) iru ati omi ninu epo (W / O).

Atọka ti o wọpọ julọ ti a lo lati wiwọn iṣẹ imulsifying jẹ iwọntunwọnsi lipophilic hydrophilic (HLB). Iwọn HLB kekere kan tọkasi pe emulsifier ni lipophilicity ti o lagbara ati pe o ni itara lati ṣe omi ninu eto epo (W / O); Iwọn HLB giga kan tọkasi hydrophilicity ti o lagbara ati pe o ni itara lati dagba epo kan ninu omi (O/W). Nitorinaa, iye HLB ni afikun kan, eyiti o le ṣee lo lati mura ipara pẹlu oriṣiriṣi iye HLB.

 

[Iru Emulsifier]

Awọn ohun elo Emulsifier ni awọn paati agbegbe meji, hydrophilic ati lipophilic. Gẹgẹbi awọn abuda agbegbe hydrophilic wọn, wọn le pin si awọn oriṣi mẹta.

1.Negative ion emulsifiers jẹ awọn emulsifiers ti o ionize ninu omi lati dagba awọn ẹgbẹ hydrophilic odi ion pẹlu alkyl tabi awọn ẹgbẹ aryl, gẹgẹbi awọn carboxylates, sulfates, ati sulfonates. Iru emulsifier yii jẹ lilo pupọ julọ ati pe o ni iwọn iṣelọpọ ti o ga julọ. Awọn ọja ti o wọpọ pẹlu ọṣẹ (C15-17H31-35CO2Na), sodium stearate (C17H35CO2Na), sodium dodecyl sulfate (C12H25OSO3Na), ati kalisiomu dodecyl benzene sulfonate (ilana igbekale: [fi sii agbekalẹ]). Awọn emulsifiers ion odi nilo lilo labẹ ipilẹ tabi awọn ipo didoju ati pe a ko le lo labẹ awọn ipo ekikan. Nigba ti a ba lo orisirisi awọn emulsifiers lati ṣeto ipara, awọn emulsifiers anionic le jẹ adalu pẹlu ara wọn tabi pẹlu awọn emulsifiers nonionic. Ioni odi ati awọn emulsifiers ion rere ko le ṣee lo papọ ni emulsion kan, bi dapọ wọn le ṣe idiwọ iduroṣinṣin ti emulsion.

2. Awọn emulsifiers ion rere ionize ninu omi lati dagba awọn ẹgbẹ hydrophilic ion rere pẹlu awọn ẹgbẹ alkyl tabi aryl. Awọn oriṣi diẹ ni iru emulsifier yii, ati pe gbogbo wọn jẹ awọn itọsẹ ti amines, gẹgẹbi N-dodecyldimethylamine, eyiti o le ṣee lo fun awọn aati polymerization.

3.Non ionic emulsifiers jẹ iru tuntun ti emulsifier ti a ṣe afihan ti kii ṣe ionization ninu omi. Ekun hydrophilic rẹ jẹ ti awọn oriṣiriṣi awọn ẹgbẹ pola, ni igbagbogbo pẹlu awọn ethers polyoxyethylene ati awọn ethers polyoxypropylene. Epo lipophilic rẹ (alkyl tabi aryl) taara sopọ mọ ether oxide ethylene. Ọja aṣoju jẹ para octylphenol polyoxyethylene ether (ilana igbekale:). Awọn ọta atẹgun lori pq polyether ti awọn emulsifiers ti kii-ionic le ṣe awọn ifunmọ hydrogen pẹlu omi, gbigba wọn laaye lati tu ninu omi. O le ṣee lo labẹ ekikan mejeeji ati awọn ipo ipilẹ, ati pe o ni ipa imulsification to dara. O jẹ lilo pupọ ni iṣelọpọ awọn kemikali, awọn aṣọ, awọn ipakokoropaeku, epo, ati latex.

 

Orisi ti emulsifiers

 

Ẹka 1: Non ionic surfactants

 

1, Awọn afikun orisun ti kii-ionic

1. Alkylphenol polyoxyethylene ether

1) Nonylphenol polyoxyethylene ether NP jara, Nongfu No.

2) Octylphenol polyoxyethylene ether emulsifier OP jara, phosphooctyl 10 (seju octylphenol polyoxyethylene ether)

3) Bis, tributylphenol polyoxyethylene ether (C4H9) - O (EO) nH

4) Alkylphenol polyoxyethylene ether polyoxyethylene propylene ether emulsifier No.. 11

5) Phenethyl phenol polyoxypropylene polyoxyethylene ether emulsifier No.. 12

 

2. Benzylphenol polyoxyethylene ether

1) 2. Tribenzyl phenol polyoxyethylene ether emulsifier BP, Wulu BP, aaye awọsanma 65-70 ℃

2) Dibenzylphenol polyoxyethylene ether Nongyu 300

3) Benzyl dimethyl phenol polyoxyethylene ether Nongyu 400

4) Dibenzyl isopropylfenyl phenol [tun mọ bi dibenzyl diphenol] polyoxyethylene ether emulsifier BC aaye awọsanma 69-71 ℃

5) Dibenzylbiphenylphenol, polyoxypropylene, polyoxyethylene ether, Ningru 31, aaye awọsanma 76-84 ℃, iwọn kekere, lilo jakejado

 

3. Phenethyl phenol polyoxyethylene ether

1) Phenethyl phenol polyoxyethylene ether agricultural wara No.. 600 ati No.. 500 yellow ni o ni awọn ti o dara ju emulsification ti Organic irawọ owurọ pẹlu ohun ethylene oxide nọmba ti 20-27 ati ki o kan awọsanma ojuami ti 83-92. Awọn oriṣi meji lo wa:

Triphenylethylphenol polyoxyethylene ether, ti o wọpọ ni awọn pato mẹta

Triphenylethylphenol/epoxyethane (ipin ipin) aaye awọsanma (1% ojutu olomi) Nọmba afikun EO

1:2.2-2.3 70-75 20-21 1:2.6-2.7 80-85 24-25
1:3.2-3.3 95-100 30-31
Bisphenethyl phenol polyoxyethylene ether

2) Phenethyl isopropylfenyl phenol polyoxyethylene ether agricultural wara 600-2 agbedemeji / EO ibi-iwọn awọsanma ojuami (1% olomi ojutu) EO nọmba afikun
1:2.1-2.3 70-75 17-18 1:2.6-2.8 85-90 20-24

3) Diphenylethyl phenol polyoxyethylene ether emulsifier BS ni awọn ohun-ini emulsifying ti o dara pẹlu awọn ipakokoropaeku irawọ owurọ 500 yellow Organic. Iwọn agbedemeji/EO ibi-ipin jẹ 1: 1.7 1: 2 1: 2.3 1: 2.6 1: 3 1: 3.5 1: 4 aaye awọsanma (1% ojutu olomi) 51 70 75 82 89 96 86 (5% CaCl2 ojutu)

4) Diphenylethyldiphenol polyoxyethylene ether

5) Phenethyl naphthol polyoxyethylene ether

 

4. Ọra oti polyoxyethylene ether ati iru awọn ọja

1) Lauryl oti polyoxyethylene ether, ti a ṣejade ni akọkọ lati inu ọti-waini agbon (eyiti o jẹ ti oti C12 julọ), pẹlu aṣoju ilaluja JFC aaye awọsanma ti 40-50 ℃ ati oluranlowo ilaluja EA

2) Isooctyl polyoxyethylene ether Igepal CA

3) Octadecanol orisun polyoxyethylene ether Pingjia jara wara ogbin No.. 200

4) Etriol polyoxyethylene ether Hirst GenapolX jara Japanese katalitiki kemistri Softanol jara

6) Ọra oti polyoxyethylene ether

 

5. Phenethyl phenol polyoxyethylene ether polyoxyethylene propylene ether ati iru awọn ọja

1) Phenethyl phenol polyoxyethylene ether EPE iru wara ogbin 1601 Ningru 33 ti a lo fun idapọ 1656L/1656H, PEP iru wara ogbin 1602 Ningru 34 ni a lo fun sisọpọ Ningru 0211/0212

2) Phenethyl phenylpropanol polyoxyethylene ether wara ogbin 1601-II aaye awọsanma 79-80 ℃, 1602- Ⅱ ℃

3) Phenethyl phenol polyoxyethylene ether

 

6. Fatty amine polyoxyethylene ether

1) Amine ọra [ti a tun mọ ni alkyl amine] ether polyoxyethylene

2) Ọra amide polyoxyethylene ether

3) Alkylamine oxide

4) Quaternary amine alkoxides ati iru awọn ọja
Ẹka keji:

Awọn afikun ester ti kii ṣe ionic

1. Fatty acid ethylene oxide adduct
1) Oleic acid polyoxyethylene ester
2) Stearic acid polyoxyethylene ester
3) Rosin acid polyoxyethylene ester

2. Castor epo epoxyethane adduct ati awọn itọsẹ rẹ, awọn emulsifiers ile nipasẹ orukọ ajeji BL, Ningru 110 120 130 140 emulsifiers EL, PC

3. Polyol fatty acid esters ati epoxyethane wọn ngbaradi ti sorbitol fatty acid esters ti o gbẹ: Span series 20 40 60 80 85 Lagbara lipophilicity
Dehydrated sorbitol fatty acid ester epoxyethane adduct: Tween jara ni solubility omi ti o ga ju Span

4. Non ionic additives da lori glycerol bi awọn ipilẹ aise ohun elo

1) Dimeric glycerol ati awọn esters fatty acid

2) Diglyceride polypropylene glycol ether

3) Glycerol polyoxyethylene ether polyoxyethylene propylene ether ọra acid ester
Ẹka pataki kẹta:

Awọn afikun ti kii ṣe ionic pẹlu awọn bulọọki hydroxyl ti pari
1. Afikun ti kii ṣe ionic pẹlu ọna-iṣapẹrẹ ati opin opin ẹgbẹ hydroxyl
2. Awọn afikun ti kii ṣe ionic pẹlu eto asymmetric ati ipari ẹgbẹ hydroxyl

 

Anionic surfactant

 

1. Sulfonic acid iyọ

 

1. Alkylbenzene sulfonate

1) iṣuu soda Dialkylbenzenesulfonate

2) Iṣuu soda alkyl aryl sulfonate

3) iṣuu soda dodecylbenzenesulfonjẹ (kalisiomu) DBS Na

 

2. Alkyl naphthalene sulfonate

1) Sodamu butyl naphthalene sulfonate Nekal A ọrinrin oluranlowo HB

2) Sodium dibutyl naphthalene sulfonate Nekal BX (lulú)

3) Iṣuu soda diisopropylnaphthalene sulfonate Morwet RP

4) Monomethyl naphthalene sulfonate sodium Morwet M

 

3. Alkyl sulfonate

1) Sodium epo sulfonate R jẹ ẹgbẹ alkyl ti o dapọ pẹlu iwuwo molikula apapọ ti 400-500

2) Sodium Alkenyl Sulfonate RCH = CHCH2SO3Na

3) Iṣuu soda hydroxyalkylsulfonate R-CH-CH2-CH2SO3NaOH

 

4. Alkyl succinate sulfonate

1) Sodium alkyl succinate sulfonate penetrant T, oluranlowo ọrinrin CB-102 (diisooctylsuccinate sulfonate), Aerosol IB (iṣuu soda dibutyl succinate sulfonate), Aerosol MA ( sodium dihexyl succinate sulfonate), Aerosol Ay (sodium dipentyl sulateccinate)

2) Alkyl polyoxyethylene ether succinate sulfonate

3) Alkylphenol polyoxyethylene ether succinate sulfonate SSOPA (Alkylphenol polyoxyethylene ether formaldehyde condensate sodium succinate sulfonate) Iranlọwọ ogbin 2000 (monoalkylphenyl polyoxyethylene ether succinate sulfanote 3% ojutu jẹ)

 

5. Alkyl biphenyl ether sulfonate

 

6. Naphthalene sulfonic acid formaldehyde condensate

1) Dispersant F fun benzyl naphthalene sulfonate formaldehyde condensate

2) Iṣuu soda naphthalene sulfonate formaldehyde condensate NNO

3) Iṣuu soda dibutylenesulfonate formaldehyde condensate dispersant NỌ

4) Methyl naphthalene sulfonate soda formaldehyde condensate MF

 

7. N-methyl fatty amide orisun bovine sulfonate detergent 209 pancreatic leefofo T

8. N-alkylacyl sarcosinate Lissapol LS detergent

9.Isopropyl sulfate itọsẹ

 

2, Sulfate

1. Sulfated castor epo Türkiye epo pupa

2. Ọra oti imi-ọjọ ROSO3Na

1) Sodium Lauryl Sulfate ti a ṣe atunṣe

2) iṣuu soda cetamol imi-ọjọ C16H33SO3Na

3) iṣuu soda secondary oti imi-ọjọ H2n + 1CH (CH3) OSO3Na

4) Oti ọti oyinbo ti o dapọ (C12-14) imi-ọjọ soda

3. Oti ọra polyoxyethylene ether sulfate Maprofix ES (sodium lauryl alcohol polyoxyethylene ether sulfate)
4. Alkyl phenol polyoxyethylene ether sulfate RO (EO) nSO3Na awọn ẹgbẹ alkyl ti o wọpọ jẹ nonyl ati octyl.

5. Aromati alkylphenol polyoxyethylene ether sulfate

3, Phosphate ati hypophosphite

1. Alkylphenol polyoxyethylene ether fosifeti OO RO (EO) np - (OH) 2 [RO (EO) n] 2-P - (OH) 2 monoester diester
Ni lọwọlọwọ jara meji: R=C8H17 OPEPO4 ati R=C9H19 NPEPO4
Orukọ Ọja: Phenolic Ether Phosphate Surfactant MAPP (Monoester), NPEPO4Na (tabi K)

2.Phenethylphenol polyoxyethylene ether fosifeti ester (free acid type) koodu SPEnPO4 O [- CHCH3] KO (EO) np - (OH) 2 [[- CHCH3] KO (EO) n] 2-P - (OH) 2 monoester diester

3. Fatty acid polyoxyethylene ester fosifeti
4. Alkyl fosifeti, aryl fosifeti O
5. Alkylamine polyoxyethylene ether fosifeti ester R = C12-14 n = 10-16 monoester, tun mo bi surfactant MAPRO (EO) np - (OH) 2
6. Ọra oti polyoxyethylene ether fosifeti ester
4, Carboxylate (carboxylate ọra) gẹgẹbi awọn afikun ọṣẹ rosin acid polymer

1, Non-ionic iru
1. Alkylphenol polyoxyethylene ether formaldehyde condensate Nongfu 700

2. 1) Phenylalkylphenol polyoxyethylene ether formaldehyde condensate Ningru No.. 36, Nongli No.. 700-1 Nongli SPF 2) isopropylphenol polyoxyethylene ether formaldehyde condensate Nongli No.. 700-2, Ningru No.37 3) Benzylphenol polyoxyethylene ether formaldehyde condensate Japan Sorpol PPB150, 200

1) Phenethyl phenol polyoxyethylene ether formaldehyde condensate Ningru 36 ati Nongfu 700-1 Nongfu SPF

2) Isopropyl phenyl phenol polyoxyethylene ether formaldehyde condensate Nongjiu 700-2 ati Ningru 37

3) Benzylphenol polyoxyethylene ether formaldehyde condensate Japan Sorpol PPB150,200

3. Biphenylphenol polyoxyethylene ether formaldehyde condensate

4. Polyvinyl oti pẹlu pipe hydrolysis jẹ 98-99%, ati awọn ìyí ti hydrolysis pẹlu apa kan hydrolysis jẹ 88-89%

5. Polyoxyethylene ati polyoxypropylene block copolymers, pẹlu polyether molikula òṣuwọn ti 2000-3000, ni o dara ninu agbara, ati awọn ti o ga molikula òṣuwọn ni dara dispersibility, gẹgẹ bi awọn epoxyethane epoxybutane copolymer ati epoxyethane epoxypropane epoxybutane copolymer.

2, Anionic iru
1. Polycarboxylate polyacrylic acid, sodium polyacrylate, polyacrylamide

2. Alkylphenol polyoxyethylene ether formaldehyde condensate sulfate SOPA-II (270) SOPA-V (570)

3. Alkyl naphthalene sulfonate formaldehyde condensate ati awọn iru rẹ iru MF MSF
4. Phenol formaldehyde condensate sulfonate ati awọn iru rẹ iru
5. Methylcellulose ati awọn itọsẹ rẹ
6. Xanthan gomu XG
7. Lignosulfonate iṣuu soda Lignosulfonate M-9, 16 Deglycosylated iṣuu soda Lignosulfonate M-10 Lignosulfonate iṣuu soda M-14 Didi títúnṣe iṣuu soda Lignosulfonate M-13, 15 Deglycosylated iṣuu soda Lignosulfonate M-17

Cationic surfactant

1, Ammonium iyọ iru

1. Alkyl ammonium iyọ iru

2. Amino oti ọra acid itọsẹ iru

3. Polyamine fatty acid itọsẹ iru
4. Iru Imidazoline

2, Quaternary ammonium iyọ iru

1. Alkyl trimethylammonium iyọ iru dodecyl trimethylammonium kiloraidi 1231 Hexadecyltrimethylammonium kiloraidi 1631 Octadecyltrimethylammonium kiloraidi 1831
2. Dialkyldimethylammonium iyọ iru
3. Alkyl dimethyl benzyl ammonium iyọ iru dodecyl dimethyl benzyl ammonium kiloraidi 1227 acrylic dyeing agent TAN
4. Pyridine iyọ iru
5. Alkyl isoquinoline iyọ fọọmu
6. Benzyl kiloraidi amine iru

Amphoteric surfactant

1, Amino acid iru

1. Alanine iru

2. Glycine Iru II, betaine Iru III, imidazoline iru IV, ati amine oxide jẹ iru si amphoteric surfactants, ni ibamu pẹlu mejeeji anionic surfactants ati cationic ati nonionic surfactants. Wọn ṣe afihan awọn ohun-ini ti kii-ionic ni alabọde ati awọn solusan ipilẹ ati awọn ohun-ini cationic ti ko lagbara ni awọn ojutu ekikan.

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